ChemInform Abstract: Rh I ‐Catalyzed Site‐Selective Decarbonylative Alkenylation and Arylation of Quinolones under Chelation Assistance
An N‐pyrimidinyl substituent in the substrate is found to redirect the coordination between catalyst and the carbonyl group to cause a direct C—H functionalization at position 2 of the 4‐quinolinones.
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| Veröffentlicht in: | ChemInform 2015-11, Vol.46 (44) |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | An N‐pyrimidinyl substituent in the substrate is found to redirect the coordination between catalyst and the carbonyl group to cause a direct C—H functionalization at position 2 of the 4‐quinolinones. |
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| ISSN: | 0931-7597 1522-2667 |
| DOI: | 10.1002/chin.201544169 |