ChemInform Abstract: γ-Aminoalcohol Rearrangement Applied to Pentahydroxylated Azepanes Provides Pyrrolidines Epimeric to HomoDMDP

ChemInform Abstract: γ-Aminoalcohol Rearrangement Applied to Pentahydroxylated Azepanes Provides Pyrrolidines Epimeric to HomoDMDP

A short sequence is described for the conversion of azepanes (I) and (V) into pyrrolidines (IV) and (VIII), which are epimeric to α‐glucosidase inhibitor homoDMDP.

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Bibliographische Detailangaben
Veröffentlicht in:ChemInform 2015-07, Vol.46 (28), p.no-no
Hauptverfasser: Jagadeesh, Y., Tran, A. T., Luo, B., Auberger, N., Desire, J., Nakagawa, S., Kato, A., Zhang, Y., Sollogoub, M., Bleriot, Y.
Format: Artikel
Sprache:eng
Schlagworte:
pyrrole derivatives
ring contraction
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Beschreibung
Zusammenfassung:A short sequence is described for the conversion of azepanes (I) and (V) into pyrrolidines (IV) and (VIII), which are epimeric to α‐glucosidase inhibitor homoDMDP.
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201528140