ChemInform Abstract: Coordination Preferences of the Alkali Cations Sodium and Caesium in the Mixed‐Cationic Zintl Ammoniate Cs 3.2 Na 0.8 Ge 9 ·5.3NH 3

Crystals of the title compound are prepared by condensation of NH 3 onto a mixture of Na 2 Cs 2 Ge 9 (obtained from the elements at 743.15 K for 72 h) and dibenzo‐18‐crown‐6, followed by storage of the reaction mixture for one year at 235.15 K.

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Veröffentlicht in:ChemInform 2015-01, Vol.46 (1)
Hauptverfasser: Gaertner, Stefanie, Suchentrunk, Christof, Korber, Nikolaus
Format: Artikel
Sprache:eng
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Zusammenfassung:Crystals of the title compound are prepared by condensation of NH 3 onto a mixture of Na 2 Cs 2 Ge 9 (obtained from the elements at 743.15 K for 72 h) and dibenzo‐18‐crown‐6, followed by storage of the reaction mixture for one year at 235.15 K.
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201501004