ChemInform Abstract: Stereoselective Formation of (E)-β-Alkoxy Acrylates from Fischer Carbene Complexes and Chelated Amino Acid Ester Enolates

The reaction between chelated ester enolates and alkyl Fischer carbene complexes is characterized by a nucleophilic attack on the electrophilic carbene center.

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Bibliographische Detailangaben
Veröffentlicht in:	ChemInform 2014-09, Vol.45 (36), p.no-no
Hauptverfasser:	Chaudhuri, Rupsha, Kazmaier, Uli
Format:	Artikel
Sprache:	eng
Schlagworte:	hydroxycarboxylic acids (ether carboxylic acids) (acyclic compounds) and esters reactions of organo-metal compounds
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	The reaction between chelated ester enolates and alkyl Fischer carbene complexes is characterized by a nucleophilic attack on the electrophilic carbene center.
ISSN:	0931-7597 1522-2667
DOI:	10.1002/chin.201436068