ChemInform Abstract: Dicobalt-μ-oxo Polyoxometalate Compound, [(α2-P2W17O61Co) 2O]14-: A Potent Species for Water Oxidation, C-H Bond Activation, and Oxygen Transfer

ChemInform Abstract: Dicobalt-μ-oxo Polyoxometalate Compound, [(α2-P2W17O61Co) 2O]14-: A Potent Species for Water Oxidation, C-H Bond Activation, and Oxygen Transfer

The highly reactive species [(α2‐P2W17O61Co) 2O]14‐ containing a nearly linear Co—O—Co moiety is prepared by oxidation of [α2‐P2W17O61Co II(H2O)]8‐ and characterized by single crystal XRD, 31 NMR, Raman, and UV/VIS spectroscopy, and DFT calculations.

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Bibliographische Detailangaben
Veröffentlicht in:ChemInform 2014-04, Vol.45 (16), p.no-no
Hauptverfasser: Barats-Damatov, Delina, Shimon, Linda J. W., Weiner, Lev, Schreiber, Roy E., Jimenez-Lozano, Pablo, Poblet, Josep M., de Graaf, Coen, Neumann, Ronny
Format: Artikel
Sprache:eng
Schlagworte:
cobalt
cobalt, Co
phosphorus
phosphorus, P
potassium
potassium, K
tungsten
tungsten, W
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Zusammenfassung:The highly reactive species [(α2‐P2W17O61Co) 2O]14‐ containing a nearly linear Co—O—Co moiety is prepared by oxidation of [α2‐P2W17O61Co II(H2O)]8‐ and characterized by single crystal XRD, 31 NMR, Raman, and UV/VIS spectroscopy, and DFT calculations.
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201416022