ChemInform Abstract: Iron‐Catalyzed Highly Enantioselective Reduction of Aromatic Ketones with Chiral P 2 N 4 ‐Type Macrocycles

ChemInform Abstract: Iron‐Catalyzed Highly Enantioselective Reduction of Aromatic Ketones with Chiral P 2 N 4 ‐Type Macrocycles

The catalytic system in situ generated from the iron carbonyl complex and chiral 22‐membered tetraazadiphospha‐macrocycle PAC exhibits high activity and excellent enantioselectivity in the transfer hydrogenation of various aromatic ketones.

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Veröffentlicht in:ChemInform 2012-08, Vol.43 (33)
Hauptverfasser: Yu, Shenluan, Shen, Weiyi, Li, Yanyun, Dong, Zhenrong, Xu, Yaqing, Li, Qi, Zhang, Juanni, Gao, Jingxing
Format: Artikel
Sprache:eng
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Zusammenfassung:The catalytic system in situ generated from the iron carbonyl complex and chiral 22‐membered tetraazadiphospha‐macrocycle PAC exhibits high activity and excellent enantioselectivity in the transfer hydrogenation of various aromatic ketones.
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201233025