ChemInform Abstract: Counterion Influence on the Vibrational Wavenumbers in Ternary and Quaternary Metal Hydride Salts, A 2 MH 6 (A: Alkali Metal, Alkaline Earth, and Lanthanides; M: Ir, Fe, Ru, Os, Pt, Mn)
The wavenumbers of the ν 3 metal—hydrogen stretching mode in the IR spectra of [MnH 6 ] 5‐ , [FeH 6 ] 4‐ , [RuH 6 ] 4‐ , [OsH 6 ] 4‐ , [IrH 6 ] 3‐ , and [PtH 6 ] 2‐ linearly depend on the ionization energies of the counterions (alkali metal, alkaline earth, lanthanoid) with a separate line for each...
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| Veröffentlicht in: | ChemInform 2012-04, Vol.43 (16) |
|---|---|
| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The wavenumbers of the ν
3
metal—hydrogen stretching mode in the IR spectra of [MnH
6
]
5‐
, [FeH
6
]
4‐
, [RuH
6
]
4‐
, [OsH
6
]
4‐
, [IrH
6
]
3‐
, and [PtH
6
]
2‐
linearly depend on the ionization energies of the counterions (alkali metal, alkaline earth, lanthanoid) with a separate line for each metal. |
|---|---|
| ISSN: | 0931-7597 1522-2667 |
| DOI: | 10.1002/chin.201216006 |