ChemInform Abstract: Enantioselective Organocatalytic Formal Allylation of α-Branched Aldehydes

Enantioselective Michael addition of sulfone (I) to aldehydes (II) in the presence of 4‐nitrobenzoic acid and 9‐amino‐9‐deoxyepiquinine as catalytic system is achieved.

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Bibliographische Detailangaben
Veröffentlicht in:	ChemInform 2012-02, Vol.43 (9), p.no-no
Hauptverfasser:	Rodrigo, Eduardo, Morales, Sara, Duce, Sara, Garcia Ruano, Jose Luis, Cid, M. Belen
Format:	Artikel
Sprache:	eng
Schlagworte:	aldehydes (benzene compounds) C-C bond formation diastereoselective syntheses diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism) enantioselective syntheses (incl. cis/trans-isomerism) organocatalysis
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Beschreibung
Zusammenfassung:	Enantioselective Michael addition of sulfone (I) to aldehydes (II) in the presence of 4‐nitrobenzoic acid and 9‐amino‐9‐deoxyepiquinine as catalytic system is achieved.
ISSN:	0931-7597 1522-2667
DOI:	10.1002/chin.201209022