ChemInform Abstract: An α-Diaminoboryl Carbanion Assisted Stereoselective Single-Pot Preparation of α,β-Disubstituted Acrylonitriles

ChemInform Abstract: An α-Diaminoboryl Carbanion Assisted Stereoselective Single-Pot Preparation of α,β-Disubstituted Acrylonitriles

Two efficient methods are reported: the use of aromatic and conjugated aldehydes predominantly leads to (Z)‐isomers, whereas with aliphatic aldehydes the (E)‐isomers are mainly formed.

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Veröffentlicht in:ChemInform 2012-01, Vol.43 (4), p.no-no
Hauptverfasser: Tomioka, Takashi, Sankranti, Rambabu, Vaughan, Trey G., Maejima, Toshihide, Yanase, Takayoshi
Format: Artikel
Sprache:eng
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alkenes (benzene compounds)
e/z-selectivity (incl. e/z-isomerism)
nitriles (acyclic compounds)
polyphenylalkene derivatives (stilbene derivatives)
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container_issue 4
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container_title ChemInform
container_volume 43
creator Tomioka, Takashi
Sankranti, Rambabu
Vaughan, Trey G.
Maejima, Toshihide
Yanase, Takayoshi
description Two efficient methods are reported: the use of aromatic and conjugated aldehydes predominantly leads to (Z)‐isomers, whereas with aliphatic aldehydes the (E)‐isomers are mainly formed.
doi_str_mv 10.1002/chin.201204045
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source Wiley Online Library Journals Frontfile Complete
subjects alkenes (benzene compounds)
e/z-selectivity (incl. e/z-isomerism)
nitriles (acyclic compounds)
polyphenylalkene derivatives (stilbene derivatives)
title ChemInform Abstract: An α-Diaminoboryl Carbanion Assisted Stereoselective Single-Pot Preparation of α,β-Disubstituted Acrylonitriles
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