ChemInform Abstract: An α-Diaminoboryl Carbanion Assisted Stereoselective Single-Pot Preparation of α,β-Disubstituted Acrylonitriles

Two efficient methods are reported: the use of aromatic and conjugated aldehydes predominantly leads to (Z)‐isomers, whereas with aliphatic aldehydes the (E)‐isomers are mainly formed.

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Bibliographische Detailangaben
Veröffentlicht in:	ChemInform 2012-01, Vol.43 (4), p.no-no
Hauptverfasser:	Tomioka, Takashi, Sankranti, Rambabu, Vaughan, Trey G., Maejima, Toshihide, Yanase, Takayoshi
Format:	Artikel
Sprache:	eng
Schlagworte:	alkenes (benzene compounds) e/z-selectivity (incl. e/z-isomerism) nitriles (acyclic compounds) polyphenylalkene derivatives (stilbene derivatives)
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	Two efficient methods are reported: the use of aromatic and conjugated aldehydes predominantly leads to (Z)‐isomers, whereas with aliphatic aldehydes the (E)‐isomers are mainly formed.
ISSN:	0931-7597 1522-2667
DOI:	10.1002/chin.201204045