ChemInform Abstract: Asymmetric Trienamine Catalysis for the Construction of Structurally Rigid Cyclic α,α-Disubstituted Amino Acid Derivatives

ChemInform Abstract: Asymmetric Trienamine Catalysis for the Construction of Structurally Rigid Cyclic α,α-Disubstituted Amino Acid Derivatives

In the presence of a secondary amine catalyst, 2,4‐dienals undergo highly regio‐ and stereoselective Diels—Alder reactions with olefinic azlactones.

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:ChemInform 2011-12, Vol.42 (52), p.no-no
Hauptverfasser: Jiang, Hao, Gschwend, Bjoern, Albrecht, Lukasz, Hansen, Signe Grann, Joergensen, Karl Anker
Format: Artikel
Sprache:eng
Schlagworte:
aminocarboxylic acids (hydrazinocarboxylic acids) and esters (benzene compounds)
cycloaddition reactions
diastereoselective syntheses
diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism)
enantioselective syntheses (incl. cis/trans-isomerism)
oxazole derivatives
ring closure reactions
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:In the presence of a secondary amine catalyst, 2,4‐dienals undergo highly regio‐ and stereoselective Diels—Alder reactions with olefinic azlactones.
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201152123