ChemInform Abstract: Enantio- and Diastereoselective Synthesis of (E)-1,5-syn-Diols: Application to the Synthesis of the C(23)-C(40) Fragment of Tetrafibricin

Chiral Soderquist borane is used to prepare various chiral diols in a one‐pot three‐step reaction of allenyl trifluoroborate (I) with two different aldehydes.

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Bibliographische Detailangaben
Veröffentlicht in:	ChemInform 2011-07, Vol.42 (27), p.no-no
Hauptverfasser:	Kister, Jeremy, Nuhant, Philippe, Lira, Ricardo, Sorg, Achim, Roush, William R.
Format:	Artikel
Sprache:	eng
Schlagworte:	alcohols (acyclic compounds) alcohols (benzene compounds) diastereoselective syntheses diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism) enantioselective syntheses (incl. cis/trans-isomerism)
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Beschreibung
Zusammenfassung:	Chiral Soderquist borane is used to prepare various chiral diols in a one‐pot three‐step reaction of allenyl trifluoroborate (I) with two different aldehydes.
ISSN:	0931-7597 1522-2667
DOI:	10.1002/chin.201127068