ChemInform Abstract: Influence of Geminal Disubstitution on Samarium Diiodide Induced Reductive Cyclizations of γ-Aryl Ketones

ChemInform Abstract: Influence of Geminal Disubstitution on Samarium Diiodide Induced Reductive Cyclizations of γ-Aryl Ketones

Geminal disubstitution at the β‐ and γ‐position of the alkyl chain of γ‐aryl ketones significantly increases the yield compared to unsubstituted ketones.

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Veröffentlicht in:ChemInform 2011-06, Vol.42 (26), p.no-no
Hauptverfasser: Niermann, Andre, Reissig, Hans-Ulrich
Format: Artikel
Sprache:eng
Schlagworte:
diastereoselective syntheses
diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism)
enantioselective syntheses (incl. cis/trans-isomerism)
hydrogenated naphthalene derivatives
ring closure reactions
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Beschreibung
Zusammenfassung:Geminal disubstitution at the β‐ and γ‐position of the alkyl chain of γ‐aryl ketones significantly increases the yield compared to unsubstituted ketones.
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201126092