ChemInform Abstract: Autoxidative Annulation Cascade of the α-Cyano β-TMS-Capped Alkynyl Cycloalkanone System

The presence of the trimethylsilyl moiety and a cyano group are essential for the annulation as no autooxidative cyclization takes place using the terminal alkyne (XI) or ester (XII).

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Bibliographische Detailangaben
Veröffentlicht in:	ChemInform 2011-05, Vol.42 (21), p.no-no
Hauptverfasser:	Wong, Ying-Chieh, Hsieh, Min-Tsang, Amancha, Prashanth K., Chin, Chih-Lung, Liao, Cheng-Feng, Kuo, Chun-Wei, Shia, Kak-Shan
Format:	Artikel
Sprache:	eng
Schlagworte:	cyclopentane derivatives diastereoselective syntheses diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism) enantioselective syntheses (incl. cis/trans-isomerism) indan derivatives ring closure reactions rings with 7 or more members
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Beschreibung
Zusammenfassung:	The presence of the trimethylsilyl moiety and a cyano group are essential for the annulation as no autooxidative cyclization takes place using the terminal alkyne (XI) or ester (XII).
ISSN:	0931-7597 1522-2667
DOI:	10.1002/chin.201121060