ChemInform Abstract: Stabilization of Th 3+ Ions into Mixed‐Valence Thorium Fluoride

Li 2+x Th 12 F 50 (0 < x < 1.8) is prepared by solid state reaction of an 1:4 mixture of LiF and ThF 4 (Pt tube, 550 °C, 72 h) and characterized by powder XRD, 7 Li MAS NMR and EPR spectroscopy, and cyclic voltammetry.

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Veröffentlicht in:ChemInform 2011-05, Vol.42 (18)
Hauptverfasser: Dubois, Marc, Dieudonne, Belto, Mesbah, Adel, Bonnet, Pierre, El‐Ghozzi, Malika, Renaudin, Guillaume, Avignant, Daniel
Format: Artikel
Sprache:eng
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Zusammenfassung:Li 2+x Th 12 F 50 (0 < x < 1.8) is prepared by solid state reaction of an 1:4 mixture of LiF and ThF 4 (Pt tube, 550 °C, 72 h) and characterized by powder XRD, 7 Li MAS NMR and EPR spectroscopy, and cyclic voltammetry.
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201118013