ChemInform Abstract: Stereospecific Decarboxylative Allylation of Sulfones

Pd‐catalyzed decarboxylative allylation of sulfonylacetic esters proceeds stereospecifically to give tertiary homoallylic sulfones (II), (IV) in excellent yields and with almost complete retention of enantioselectivities.

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Bibliographische Detailangaben
Veröffentlicht in:	ChemInform 2011-01, Vol.42 (3), p.no-no
Hauptverfasser:	Weaver, Jimmie D., Ka, Being J., Morris, David K., Thompson, Ward, Tunge, Jon A.
Format:	Artikel
Sprache:	eng
Schlagworte:	decarboxylation diastereoselective syntheses diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism) enantioselective syntheses (incl. cis/trans-isomerism) sulfenes and derivatives (benzene compounds) sulfones sulfoxides sulfoxides, sulfones, sulfenes and derivatives (benzene compounds)
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Beschreibung
Zusammenfassung:	Pd‐catalyzed decarboxylative allylation of sulfonylacetic esters proceeds stereospecifically to give tertiary homoallylic sulfones (II), (IV) in excellent yields and with almost complete retention of enantioselectivities.
ISSN:	0931-7597 1522-2667
DOI:	10.1002/chin.201103050