ChemInform Abstract: Highly Selective Metalations of Pyridines and Related Heterocycles Using New Frustrated Lewis Pairs or tmp‐Zinc and tmp‐Magnesium Bases with BF 3 ·OEt 2

Complementary functionalizations of the heterocycles are achieved by performance of the metalations using different hindered metal amide bases in the presence or absence of BF 3 ·OEt 2 .

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Veröffentlicht in:ChemInform 2010-12, Vol.41 (50)
Hauptverfasser: Jaric, Milica, Haag, Benjamin A., Unsinn, Andreas, Karaghiosoff, Konstantin, Knochel, Paul
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
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Zusammenfassung:Complementary functionalizations of the heterocycles are achieved by performance of the metalations using different hindered metal amide bases in the presence or absence of BF 3 ·OEt 2 .
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201050145