ChemInform Abstract: Reaction of Thiocamphor with Disulfur Dichloride: Novel Formation of α-Disulfine

ChemInform Abstract: Reaction of Thiocamphor with Disulfur Dichloride: Novel Formation of α-Disulfine

Reaction of thiocamphor (I) with disulfur dichloride affords six‐ and seven‐membered tricyclic polysulfanes (II) and (III), respectively, which are oxidized by MCPBA to give bicyclic (E,E)‐α‐disulfine (IV) stereoselectively.

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Veröffentlicht in:ChemInform 2010-11, Vol.41 (47), p.no-no
Hauptverfasser: Okuma, Kentaro, Tsubota, Toshiaki, Tabuchi, Miki, Kanto, Masayuki, Nagahora, Noriyoshi, Shioji, Kosei, Yokomori, Yoshinobu
Format: Artikel
Sprache:eng
Schlagworte:
other 6-membered heterocycles (with 3 or more heteroatoms)
S-alkylation
sulfonation
sulfuration
sulfuration, sulfonation, S‐alkylation
terpenes
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Zusammenfassung:Reaction of thiocamphor (I) with disulfur dichloride affords six‐ and seven‐membered tricyclic polysulfanes (II) and (III), respectively, which are oxidized by MCPBA to give bicyclic (E,E)‐α‐disulfine (IV) stereoselectively.
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201047180