ChemInform Abstract: Total Synthesis of Furanether B. Construction of a Hydroazulene Skeleton via a Novel [5 + 2] Cycloaddition Reaction of Silyloxyallene

ChemInform Abstract: Total Synthesis of Furanether B. Construction of a Hydroazulene Skeleton via a Novel [5 + 2] Cycloaddition Reaction of Silyloxyallene

A new synthetic method for cycloheptanone derivatives is developed on the basis of a novel [5 + 2] cycloaddition reaction using a dicobalt hexacarbonyl propargyl cation species and a silyloxyallene (II).

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Veröffentlicht in:ChemInform 2010-11, Vol.41 (47), p.no-no
Hauptverfasser: Mitachi, Katsuhiko, Yamamoto, Takashi, Kondo, Fumikatsu, Shimizu, Tadashi, Miyashita, Masaaki, Tanino, Keiji
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Sprache:eng
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cycloaddition reactions
reactions of organo-metal compounds
terpenes
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container_title ChemInform
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creator Mitachi, Katsuhiko
Yamamoto, Takashi
Kondo, Fumikatsu
Shimizu, Tadashi
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Tanino, Keiji
description A new synthetic method for cycloheptanone derivatives is developed on the basis of a novel [5 + 2] cycloaddition reaction using a dicobalt hexacarbonyl propargyl cation species and a silyloxyallene (II).
doi_str_mv 10.1002/chin.201047179
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source Wiley Online Library Journals Frontfile Complete
subjects cycloaddition reactions
reactions of organo-metal compounds
terpenes
title ChemInform Abstract: Total Synthesis of Furanether B. Construction of a Hydroazulene Skeleton via a Novel [5 + 2] Cycloaddition Reaction of Silyloxyallene
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