ChemInform Abstract: Total Synthesis of Furanether B. Construction of a Hydroazulene Skeleton via a Novel [5 + 2] Cycloaddition Reaction of Silyloxyallene

ChemInform Abstract: Total Synthesis of Furanether B. Construction of a Hydroazulene Skeleton via a Novel [5 + 2] Cycloaddition Reaction of Silyloxyallene

A new synthetic method for cycloheptanone derivatives is developed on the basis of a novel [5 + 2] cycloaddition reaction using a dicobalt hexacarbonyl propargyl cation species and a silyloxyallene (II).

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Veröffentlicht in:ChemInform 2010-11, Vol.41 (47), p.no-no
Hauptverfasser: Mitachi, Katsuhiko, Yamamoto, Takashi, Kondo, Fumikatsu, Shimizu, Tadashi, Miyashita, Masaaki, Tanino, Keiji
Format: Artikel
Sprache:eng
Schlagworte:
cycloaddition reactions
reactions of organo-metal compounds
terpenes
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Zusammenfassung:A new synthetic method for cycloheptanone derivatives is developed on the basis of a novel [5 + 2] cycloaddition reaction using a dicobalt hexacarbonyl propargyl cation species and a silyloxyallene (II).
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201047179