ChemInform Abstract: Efficient Double Bond Migration of Allylbenzenes Catalyzed by Pd(OAc)2-HFIP System with Unique Substituent Effect

The system promotes the double bond isomerization under mild conditions and generally within a short time to give the (E) isomers nearly exclusively.

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Bibliographische Detailangaben
Veröffentlicht in:	ChemInform 2010-10, Vol.41 (40), p.no-no
Hauptverfasser:	Nishiwaki, Nagatoshi, Kamimura, Ryuichiro, Shono, Kimihiro, Kawakami, Toshihiko, Nakayama, Katsuhisa, Nishino, Kohei, Nakayama, Takayuki, Takahashi, Keisuke, Nakamura, Aki, Hosokawa, Takahiro
Format:	Artikel
Sprache:	eng
Schlagworte:	alkenes (benzene compounds) e/z-selectivity (incl. e/z-isomerism) valence isomerism processes
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	The system promotes the double bond isomerization under mild conditions and generally within a short time to give the (E) isomers nearly exclusively.
ISSN:	0931-7597 1522-2667
DOI:	10.1002/chin.201040057