ChemInform Abstract: A Facile Total Synthesis of Hainanensine via an Unusual Rearrangement-Annulation Cascade

ChemInform Abstract: A Facile Total Synthesis of Hainanensine via an Unusual Rearrangement-Annulation Cascade

Formic acid mediated cascade rearrangement/annulation reaction is the key step to the preparation of alkaloid precursors (II), which are further functionalized to hainanensine (III) and its dimethyl analogue.

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Bibliographische Detailangaben
Veröffentlicht in:ChemInform 2010-09, Vol.41 (36), p.no-no
Hauptverfasser: Zhang, Zhi-Wei, Li, Wei-Dong Z.
Format: Artikel
Sprache:eng
Schlagworte:
alkaloids
rearrangements
ring closure reactions
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Beschreibung
Zusammenfassung:Formic acid mediated cascade rearrangement/annulation reaction is the key step to the preparation of alkaloid precursors (II), which are further functionalized to hainanensine (III) and its dimethyl analogue.
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201036199