ChemInform Abstract: Rhenium(I)-Catalyzed Cyclization of Silyl Enol Ethers Containing a Propargyl Carboxylate Moiety: Versatile Access to Highly Substituted Phenols

ChemInform Abstract: Rhenium(I)-Catalyzed Cyclization of Silyl Enol Ethers Containing a Propargyl Carboxylate Moiety: Versatile Access to Highly Substituted Phenols

Depending on the structure of the silyl enol ether moiety, either nucleophilic addition of the silyl enol ether moiety, or 1,2‐acyloxy migration occurs to give two kinds of substituted phenols.

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Veröffentlicht in:ChemInform 2010-09, Vol.41 (36), p.no-no
Hauptverfasser: Saito, Kodai, Onizawa, Yuji, Kusama, Hiroyuki, Iwasawa, Nobuharu
Format: Artikel
Sprache:eng
Schlagworte:
organo-silicon compounds
phenol ethers
ring closure reactions
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Beschreibung
Zusammenfassung:Depending on the structure of the silyl enol ether moiety, either nucleophilic addition of the silyl enol ether moiety, or 1,2‐acyloxy migration occurs to give two kinds of substituted phenols.
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201036069