ChemInform Abstract: Organocatalytic Asymmetric Synthesis of Polyfunctionalized 3-(Cyclohexenylmethyl)-indoles via a Quadruple Domino Friedel-Crafts-Type/Michael/Michael/Aldol Condensation Reaction

ChemInform Abstract: Organocatalytic Asymmetric Synthesis of Polyfunctionalized 3-(Cyclohexenylmethyl)-indoles via a Quadruple Domino Friedel-Crafts-Type/Michael/Michael/Aldol Condensation Reaction

The one‐pot multi‐component process involves the cascade reaction of nitroalkenes (II), indole derivatives (I) and two equivalents acrolein (III) catalyzed by a prolinol Tms‐ether derivative.

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Bibliographische Detailangaben
Veröffentlicht in:ChemInform 2010-08, Vol.41 (34), p.no-no
Hauptverfasser: Enders, Dieter, Wang, Chuan, Mukanova, Meruyert, Greb, Andreas
Format: Artikel
Sprache:eng
Schlagworte:
diastereoselective syntheses
diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism)
enantioselective syntheses (incl. cis/trans-isomerism)
indole derivatives
indole derivatives, isoindole derivatives
isoindole derivatives
multicomponent reactions
organocatalysis
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Beschreibung
Zusammenfassung:The one‐pot multi‐component process involves the cascade reaction of nitroalkenes (II), indole derivatives (I) and two equivalents acrolein (III) catalyzed by a prolinol Tms‐ether derivative.
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201034119