Cover Feature: Reactivity of Sodium Pentaphospholide Na[cyclo‐P5] towards C≡E (E=C, N, P) Triple Bonds (Chem. Eur. J. 67/2022)

Cover Feature: Reactivity of Sodium Pentaphospholide Na[cyclo‐P5] towards C≡E (E=C, N, P) Triple Bonds (Chem. Eur. J. 67/2022)

Novel, aromatic and anionic five‐membered phosphorus heterocycles have been created starting from [cyclo‐P5]−. By combining the pentaphospholide anion with isolobal or valence isoelectronic substrates, such as alkynes, nitriles or phosphaalkynes, either 1,2,3‐triphospholides, 1,3,4‐triphospholides o...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemistry : a European journal 2022-12, Vol.28 (67), p.n/a
Hauptverfasser: Petrov, Andrey, Conrad, Lawrence, Coles, Nathan T., Weber, Manuela, Andrae, Dirk, Zagidullin, Almaz, Miluykov, Vasili, Müller, Christian
Format: Artikel
Sprache:eng
Schlagworte:
cyclic voltammetry
DFT calculations
heteroferrocenes
phosphorus heterocycles
X-ray diffraction
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Novel, aromatic and anionic five‐membered phosphorus heterocycles have been created starting from [cyclo‐P5]−. By combining the pentaphospholide anion with isolobal or valence isoelectronic substrates, such as alkynes, nitriles or phosphaalkynes, either 1,2,3‐triphospholides, 1,3,4‐triphospholides or the hitherto unknown 1‐aza‐2,3,4‐triphospholides are formed, which can all serve as 6π‐electron ligands towards FeII. More information can be found in the Research Article by C. Müller and co‐workers (DOI: 10.1002/chem.202203056). Image designed and created by Andrey Petrov and Indira Kayumova.
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.202203567