Cover Feature: Ni(II) Precatalysts Enable Thioetherification of (Hetero)Aryl Halides and Tosylates and Tandem C−S/C−N Couplings (Chem. Eur. J. 48/2021)

Competent partners: π‐Allyl–nickel precatalysts supported by dialkylterphenyl phosphines efficiently couple a wide range of electrophiles including aryl iodides/bromides/chlorides and, for the first time, aryl and alkenyl tosylates with aromatic and aliphatic thiols. In addition, tandem C−S and C−N coupling of multi‐electrophile/nucleophile combinations is achieved in a completely chemoselective manner leading to highly functionalized products. More information can be found in the Full Paper by A. Prieto, M. C. Nicasio, et al. (DOI: 10.1002/chem.202101906).