Cover Feature: Cationic Zinc Hydride Catalyzed Carbon Dioxide Reduction to Formate: Deciphering Elementary Reactions, Isolation of Intermediates, and Computational Investigations (Chem. Eur. J. 26/2021)
Cooperativity between cationic zinc hydrides and triphenylborane is utilized to catalyze CO2 reduction. Elementary reactions provide insights into a general mechanism for zinc hydride promoted CO2 hydrosilylation and hydroboration. The significance of the zinc‐bound ligand denticity and the Lewis ac...
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| Veröffentlicht in: | Chemistry : a European journal 2021-05, Vol.27 (26), p.7318-7318 |
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| container_end_page | 7318 |
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| container_issue | 26 |
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| container_title | Chemistry : a European journal |
| container_volume | 27 |
| creator | Chambenahalli, Raju Bhargav, R. M. McCabe, Karl N. Andrews, Alex P. Ritter, Florian Okuda, Jun Maron, Laurent Venugopal, Ajay |
| description | Cooperativity between cationic zinc hydrides and triphenylborane is utilized to catalyze CO2 reduction. Elementary reactions provide insights into a general mechanism for zinc hydride promoted CO2 hydrosilylation and hydroboration. The significance of the zinc‐bound ligand denticity and the Lewis acid additive role in the catalytic process is highlighted. More information can be found in the Full Paper by L. Maron, A. Venugopal, et al. (DOI: 10.1002/chem.202005392). |
| doi_str_mv | 10.1002/chem.202101339 |
| format | Article |
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| language | eng |
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| source | Access via Wiley Online Library |
| subjects | carbon dioxide reduction hydroboration hydrosilylation reactive intermediates zinc hydride |
| title | Cover Feature: Cationic Zinc Hydride Catalyzed Carbon Dioxide Reduction to Formate: Deciphering Elementary Reactions, Isolation of Intermediates, and Computational Investigations (Chem. Eur. J. 26/2021) |
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