Cover Feature: Cationic Zinc Hydride Catalyzed Carbon Dioxide Reduction to Formate: Deciphering Elementary Reactions, Isolation of Intermediates, and Computational Investigations (Chem. Eur. J. 26/2021)

Cover Feature: Cationic Zinc Hydride Catalyzed Carbon Dioxide Reduction to Formate: Deciphering Elementary Reactions, Isolation of Intermediates, and Computational Investigations (Chem. Eur. J. 26/2021)

Cooperativity between cationic zinc hydrides and triphenylborane is utilized to catalyze CO2 reduction. Elementary reactions provide insights into a general mechanism for zinc hydride promoted CO2 hydrosilylation and hydroboration. The significance of the zinc‐bound ligand denticity and the Lewis ac...

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Veröffentlicht in:Chemistry : a European journal 2021-05, Vol.27 (26), p.7318-7318
Hauptverfasser: Chambenahalli, Raju, Bhargav, R. M., McCabe, Karl N., Andrews, Alex P., Ritter, Florian, Okuda, Jun, Maron, Laurent, Venugopal, Ajay
Format: Artikel
Sprache:eng
Schlagworte:
carbon dioxide reduction
hydroboration
hydrosilylation
reactive intermediates
zinc hydride
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Zusammenfassung:Cooperativity between cationic zinc hydrides and triphenylborane is utilized to catalyze CO2 reduction. Elementary reactions provide insights into a general mechanism for zinc hydride promoted CO2 hydrosilylation and hydroboration. The significance of the zinc‐bound ligand denticity and the Lewis acid additive role in the catalytic process is highlighted. More information can be found in the Full Paper by L. Maron, A. Venugopal, et al. (DOI: 10.1002/chem.202005392).
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.202101339