A New Class of C 2 ‐Symmetric Chiral Cyclopentadienyl Ligand Derived from Ferrocene Scaffold: Design, Synthesis and Application

A New Class of C 2 ‐Symmetric Chiral Cyclopentadienyl Ligand Derived from Ferrocene Scaffold: Design, Synthesis and Application

A new class of C 2 ‐symmetric, chiral cyclopentadienyl ligand based on planar chiral ferrocene backbone was developed. A series of its corresponding rhodium(I), iridium(I), and ruthenium(II) complexes were prepared as well. In addition, the rhodium(I) complexes were evaluated in the asymmetric catal...

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Veröffentlicht in:Chemistry : a European journal 2020-11, Vol.26 (64), p.14546-14550
Hauptverfasser: Liang, Hao, Vasamsetty, Laxmaiah, Li, Teng, Jiang, Jijun, Pang, Xingying, Wang, Jun
Format: Artikel
Sprache:eng
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Zusammenfassung:A new class of C 2 ‐symmetric, chiral cyclopentadienyl ligand based on planar chiral ferrocene backbone was developed. A series of its corresponding rhodium(I), iridium(I), and ruthenium(II) complexes were prepared as well. In addition, the rhodium(I) complexes were evaluated in the asymmetric catalytic intramolecular amidoarylation of olefin‐tethered benzamides via C−H activation.
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.202001814