Vanadium Hydroxide Cluster Ions in the Gas Phase: Bond-Forming Reactions of Doubly-Charged Negative Ions by SO 2 -Promoted V-O Activation
The gas-phase reactivity of doubly-charged vanadium hydroxides anions with SO has been studied by experimental and computational methods. The obtained results highlight the role of sulfur dioxide in promoting unprecedented bond-forming reactions, which produce singly-charged products by breaking the...
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| Veröffentlicht in: | Chemistry : a European journal 2017-09, Vol.23 (49), p.11752-11756 |
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| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The gas-phase reactivity of doubly-charged vanadium hydroxides anions with SO
has been studied by experimental and computational methods. The obtained results highlight the role of sulfur dioxide in promoting unprecedented bond-forming reactions, which produce singly-charged products by breaking the V
O
skeleton or a terminal V-O bond. |
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| ISSN: | 0947-6539 1521-3765 |
| DOI: | 10.1002/chem.201702165 |