Synthesis of a Thorium Tuck-In Complex, [(η5:η1-C5Me4CH2)(η5-C5Me5)Th{iPrNC(Me)NiPr}], by CH Bond Activation Initiated by (C5Me5)

Synthesis of a Thorium Tuck-In Complex, [(η5:η1-C5Me4CH2)(η5-C5Me5)Th{iPrNC(Me)NiPr}], by CH Bond Activation Initiated by (C5Me5)

Tuck in! (C5Me5)− effects alkyl CH bond activation (Th) and reduction (U) with the cationic complexes [(C5Me5)2An{iPrNC(Me)NiPr}][BPh3Me] to form the first structurally characterized thorium complex that contains a tuck‐in metalated (C5Me5CH2)2− ligand (see figure) and a trivalent metallocene amidi...

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Veröffentlicht in:Chemistry : a European journal 2009-11, Vol.15 (45), p.12204-12207
Hauptverfasser: Evans, William J., Walensky, Justin R., Ziller, Joseph W.
Format: Artikel
Sprache:eng
Schlagworte:
actinides
alkyl abstraction
CH activation
pentamethylcyclopentadienyl
reduction
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Zusammenfassung:Tuck in! (C5Me5)− effects alkyl CH bond activation (Th) and reduction (U) with the cationic complexes [(C5Me5)2An{iPrNC(Me)NiPr}][BPh3Me] to form the first structurally characterized thorium complex that contains a tuck‐in metalated (C5Me5CH2)2− ligand (see figure) and a trivalent metallocene amidinate [(C5Me5)2U{iPrNC(Me)NiPr}].
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.200901942