Coupling of Nitrogen Heteroaromatics and Alkanes without Transition Metals: A New Oxidative Cross-Coupling at CH/CH Bonds

Coupling of Nitrogen Heteroaromatics and Alkanes without Transition Metals: A New Oxidative Cross-Coupling at CH/CH Bonds

Look—no transition metal! Transition‐metal‐free systems for the direct cross‐coupling reactions of nitrogen heteroaromatics and alkanes are described. Under the influence of tBuOOtBu, pyridine N‐oxide derivatives react with alkanes to furnish the corresponding cross‐coupling products (alkylated nitr...

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Veröffentlicht in:Chemistry : a European journal 2009-01, Vol.15 (2), p.333-337
Hauptverfasser: Deng, Guojun, Ueda, Kirika, Yanagisawa, Shuichi, Itami, Kenichiro, Li, Chao-Jun
Format: Artikel
Sprache:eng
Schlagworte:
alkanes
CC coupling
CH activation
nitrogen heterocycles
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Zusammenfassung:Look—no transition metal! Transition‐metal‐free systems for the direct cross‐coupling reactions of nitrogen heteroaromatics and alkanes are described. Under the influence of tBuOOtBu, pyridine N‐oxide derivatives react with alkanes to furnish the corresponding cross‐coupling products (alkylated nitrogen heterocycles) in good yields.
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.200801893