Diboran(4)yl Groups as Ligands to Transition Metals

Diboran(4)yl Groups as Ligands to Transition Metals

Reaction of Na[(Cp)Fe(CO)2] and Na[(Cp)W(CO)3] with B2(NMe2)2Cl2 yields the first transition metal‐substituted diboranes [Cl(Me2N)B–B(NMe2)M(Cp)(CO)n] [M(Cp)(CO)n  Fe(Cp)(CO)2, W(Cp)(CO)3] (1a, b). The compounds were characterized in solution by NMR methods and in the crystal by X‐ray structural de...

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Veröffentlicht in:Chemische Berichte 1996-09, Vol.129 (9), p.1099-1101
Hauptverfasser: Braunschweig, Holger, Ganter, Beate, Koster, Margot, Wagner, Trixie
Format: Artikel
Sprache:eng
Schlagworte:
Diboranes
Transition-metal boryl complexes
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Zusammenfassung:Reaction of Na[(Cp)Fe(CO)2] and Na[(Cp)W(CO)3] with B2(NMe2)2Cl2 yields the first transition metal‐substituted diboranes [Cl(Me2N)B–B(NMe2)M(Cp)(CO)n] [M(Cp)(CO)n  Fe(Cp)(CO)2, W(Cp)(CO)3] (1a, b). The compounds were characterized in solution by NMR methods and in the crystal by X‐ray structural determination.
ISSN:0009-2940
1099-0682
DOI:10.1002/cber.19961290919