A Mass‐Spectrometric Investigation of C x NO 2 ( x =1, 2) Ions and Neutrals

A Mass‐Spectrometric Investigation of C x NO 2 ( x =1, 2) Ions and Neutrals

The isomeric [C 2 ,N,O 2 ] + ions OCNCO + , OCCNO + , and NCCO 2 − have been generated and structurally characterized on the basis of their collisional activation, charge reversal, and neutralization‐reionization mass spectra. The open‐shell neutrals formed in the neutralization step undergo facile...

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Veröffentlicht in:Chemische Berichte 1992-01, Vol.125 (1), p.279-283
Hauptverfasser: Sülzle, Detlev, O'Bannon, P. E., Schwarz, Helmut
Format: Artikel
Sprache:eng
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Zusammenfassung:The isomeric [C 2 ,N,O 2 ] + ions OCNCO + , OCCNO + , and NCCO 2 − have been generated and structurally characterized on the basis of their collisional activation, charge reversal, and neutralization‐reionization mass spectra. The open‐shell neutrals formed in the neutralization step undergo facile unimolecular decomposition. A recovery signal is obtained only for OCCNO.
ISSN:0009-2940
DOI:10.1002/cber.19921250144