Synthese und Struktur eines viergliedrigen Tellur — Stickstoff‐Rings

Synthese und Struktur eines viergliedrigen Tellur — Stickstoff‐Rings

Synthesis and Stucture of a Four‐Membered Tellurium‐Nitrogen Ring Reaction of Ph3P  NSiMe3 (1) with TeCl4 leads to (Ph3P  NTeCl3)2 (3). Single crystals of 3 were obtained by recrystallization from CH2Cl2; they contain two molecules of solvent. 3 forms a four‐membered planar Te2N2 ring with alterna...

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Veröffentlicht in:Chemische Berichte 1989-10, Vol.122 (10), p.1915-1916
Hauptverfasser: Münzenberg, Jörg, Noltemeyer, Mathias, Roesky, Herbert W.
Format: Artikel
Sprache:eng
Schlagworte:
Phosphoranes, imino
Tellurium, pentacoordinated
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Zusammenfassung:Synthesis and Stucture of a Four‐Membered Tellurium‐Nitrogen Ring Reaction of Ph3P  NSiMe3 (1) with TeCl4 leads to (Ph3P  NTeCl3)2 (3). Single crystals of 3 were obtained by recrystallization from CH2Cl2; they contain two molecules of solvent. 3 forms a four‐membered planar Te2N2 ring with alternating TeN bonds.
ISSN:0009-2940
1099-0682
DOI:10.1002/cber.19891221014