Electronic Structure and Gas-Phase Thermolysis of Substituted Tetrazolines Studied by Photoelectron Spectroscopy

The electronic structures and the gas‐phase thermolyses of tetrazolines 1 –5 have been studied by photoelectron spectroscopy. For compounds 1–4 cycloreversion to imine and methyl azide is observed, whereas compound 5 is contracted to give the respective diaziridine. To assign the PE spectra, MNDO ca...

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Veröffentlicht in:Chemische Berichte 1988-07, Vol.121 (7), p.1213-1217
Hauptverfasser: Rademacher, Paul, Carboni, Bertrand, Carrié, Robert, Heymanns, Peter, Poppek, Rainer
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Sprache:eng
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