Thermoluminescence characterization of Dy 3+ ‐activated Mg 5 (BO 3 ) 3 F low Z eff phosphor
Thermoluminescence characteristics of Dy 3+ ‐activated Mg 5 (BO 3 ) 3 F low Z eff phosphor are described. The Mg 5 (BO 3 ) 3 F phosphor doped with Dy 3+ as activator was prepared by the modified solid‐state reaction. Formation of the compound was confirmed by use of X‐ray powder diffraction. The X‐r...
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Veröffentlicht in: | Luminescence (Chichester, England) England), 2013-09, Vol.28 (5), p.751-754 |
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Hauptverfasser: | , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Thermoluminescence characteristics of Dy
3+
‐activated Mg
5
(BO
3
)
3
F low Z
eff
phosphor are described. The Mg
5
(BO
3
)
3
F phosphor doped with Dy
3+
as activator was prepared by the modified solid‐state reaction. Formation of the compound was confirmed by use of X‐ray powder diffraction. The X‐ray powder diffraction pattern of the as‐prepared compound shows a good match with the available JCPDS data. The γ‐irradiated Mg
5
(BO
3
)
3
F:Dy
3+
phosphor shows a simple glow curve peaking at about 148°C indicating that only one type of trap is being activated within a particular temperature range. The kinetic parameters, including activation energy and frequency factor were determined using Chen's method. The activation energy and frequency factors were 0.75 eV and 4.508 × 10
9
/s respectively. The Z
eff
of Mg
5
(BO
3
)
3
F:Dy
3+
phosphor was 9.84. Copyright © 2012 John Wiley & Sons, Ltd. |
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ISSN: | 1522-7235 1522-7243 |
DOI: | 10.1002/bio.2430 |