Synthesis of atactic polypropylene: Propylene polymerization reactions with TiCl 4 –Al(C 2 H 5 ) 2 Cl/Mg(C 4 H 9 ) 2 catalyst

The Ziegler catalyst, a combination of TiCl 4 and Al(C 2 H 5 ) 2 Cl, is a very poor catalyst for propylene polymerization. However, the addition of Mg(C 4 H 9 ) 2 to the Ziegler catalyst at a [Mg]:[Al] molar ratio 

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Veröffentlicht in:Journal of applied polymer science 2019-07, Vol.136 (25)
Hauptverfasser: Rishina, Laura А., Kissin, Yury V., Lalayan, Svetlana S., Krasheninnikov, Vadim G.
Format: Artikel
Sprache:eng
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Zusammenfassung:The Ziegler catalyst, a combination of TiCl 4 and Al(C 2 H 5 ) 2 Cl, is a very poor catalyst for propylene polymerization. However, the addition of Mg(C 4 H 9 ) 2 to the Ziegler catalyst at a [Mg]:[Al] molar ratio 
ISSN:0021-8995
1097-4628
DOI:10.1002/app.47692