Synthesis of atactic polypropylene: Propylene polymerization reactions with TiCl 4 –Al(C 2 H 5 ) 2 Cl/Mg(C 4 H 9 ) 2 catalyst
The Ziegler catalyst, a combination of TiCl 4 and Al(C 2 H 5 ) 2 Cl, is a very poor catalyst for propylene polymerization. However, the addition of Mg(C 4 H 9 ) 2 to the Ziegler catalyst at a [Mg]:[Al] molar ratio
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Veröffentlicht in: | Journal of applied polymer science 2019-07, Vol.136 (25) |
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Hauptverfasser: | , , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | The Ziegler catalyst, a combination of TiCl
4
and Al(C
2
H
5
)
2
Cl, is a very poor catalyst for propylene polymerization. However, the addition of Mg(C
4
H
9
)
2
to the Ziegler catalyst at a [Mg]:[Al] molar ratio |
---|---|
ISSN: | 0021-8995 1097-4628 |
DOI: | 10.1002/app.47692 |