A method for determining the optimum peroxide-to-amine ratio for self-curing resins

The rate of polymerization of a methacrylate monomer was influenced by the molar ratio of benzoyl peroxide to an aromatic tertiary amine accelerator when the product of the concentrations of these was kept constant. The maximum rate, measured as the minimum gel time, occurred in monomer solutions co...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Journal of applied polymer science 1973-07, Vol.17 (7), p.2213-2222
Hauptverfasser: Bowen, R. L., Argentar, H.
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The rate of polymerization of a methacrylate monomer was influenced by the molar ratio of benzoyl peroxide to an aromatic tertiary amine accelerator when the product of the concentrations of these was kept constant. The maximum rate, measured as the minimum gel time, occurred in monomer solutions containing about 1.5 moles of peroxide per mole of amine.
ISSN:0021-8995
1097-4628
DOI:10.1002/app.1973.070170720