Radical polymerization of N-vinylcaprolactam in homogeneous solution. II

Radical polymerization of N-vinylcaprolactam in homogeneous solution. II

The polymerization of N‐vinylcaprolactam in toluene, dioxane, chlorobenzene, dimethylformamide, and ethylene carbonate with various peroxides, perbenzoates and azobisisobutyronitrile as initiators at 60–80°C, was studied. Under these conditions azobisisobutyronitrile and tert‐butyl perbenzoate have...

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Veröffentlicht in:Journal of applied polymer science 1969-01, Vol.13 (1), p.1-7
Hauptverfasser: Solomon, O. F., Vasilescu, D. S., Tǎrǎrescu, V.
Format: Artikel
Sprache:eng
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Zusammenfassung:The polymerization of N‐vinylcaprolactam in toluene, dioxane, chlorobenzene, dimethylformamide, and ethylene carbonate with various peroxides, perbenzoates and azobisisobutyronitrile as initiators at 60–80°C, was studied. Under these conditions azobisisobutyronitrile and tert‐butyl perbenzoate have satisfactory activity as initiators. Under these conditions N‐vinylcaprolactam polymerization in homogeneous solution is first order towards the monomer and 0.5 order towards the initiators.
ISSN:0021-8995
1097-4628
DOI:10.1002/app.1969.070130101