Adsorption of cis-1,4-polyisoprene at solid/liquid interface
The adsorption of cis‐1,4‐polyisoprene on alumina and silica gel was studied at three temperatures. The solvents used were toluene, chlorobenzene and various mixtures of both. The adsorption from the mixtures of the solvents was much less than from either of the pure solvents. The amount of adsorpti...
Gespeichert in:
| Veröffentlicht in: | Die Angewandte makromolekulare Chemie 1994-03, Vol.220 (1), p.21-37 |
|---|---|
| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 37 |
|---|---|
| container_issue | 1 |
| container_start_page | 21 |
| container_title | Die Angewandte makromolekulare Chemie |
| container_volume | 220 |
| creator | Vangani, Veena Rakshit, Animesh Kumar |
| description | The adsorption of cis‐1,4‐polyisoprene on alumina and silica gel was studied at three temperatures. The solvents used were toluene, chlorobenzene and various mixtures of both. The adsorption from the mixtures of the solvents was much less than from either of the pure solvents. The amount of adsorption was an inverse function of temperature. The thermodynamic quantities of adsorption at infinite dilution were obtained by extrapolation and at isosteric conditions. They were computed and discussed for all the systems.
Die Adsorption von Poly(cis‐1,4‐isopren) an Aluminiumoxid‐ und Siliziumdioxid‐Oberflächen wurde bei verschiedenen Temperaturen untersucht. Die Adsorptionsausbeute verhielt sich umgekehrt proportional zur Temperatur und war aus Toluol‐ und Chlorbenzol‐Lösungen größer als aus Mischungen von Toluol und Chlorbenzol. Die thermodynamischen Adsorptionsparameter bei unendlicher Verdünnung und isosteren Bedingungen wurden durch Extrapolation ermittelt und für alle untersuchten Systeme diskutiert. |
| doi_str_mv | 10.1002/apmc.1994.052200103 |
| format | Article |
| fullrecord | <record><control><sourceid>wiley_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1002_apmc_1994_052200103</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>APMC052200103</sourcerecordid><originalsourceid>FETCH-LOGICAL-c3403-4ee6392d7a7542226fcc8395f4d1fb6dfb4dcc2566e367416f9495b93bebdd23</originalsourceid><addsrcrecordid>eNqNj8tKAzEUQIMoWKtf4GY-wLR5TwMilMG2QqsuCi5DJg-ITpsxGbH9e6dUiktX997FOZcDwC1GI4wQGet2Y0ZYSjZCnBCEMKJnYID7HUqO-DkYIIQopJiJS3CV83t_SoHpANxPbY6p7ULcFtEXJmSI7xhsY7MPObbJbV2huyLHJthxEz6_gi3CtnPJa-OuwYXXTXY3v3MI1rPHdbWAy5f5UzVdQkNZ_5Y5J6gkttQlZ4QQ4Y2ZUMk9s9jXwvqaWWMIF8JRUTIsvGSS15LWrraW0CGgR61JMefkvGpT2Oi0VxipQ7869KtDvzr199TDkfoOjdv_B1HT11X1VwCPgpA7tzsJdPpQoqQlV2_Pc8VmYoKqxUqV9AcG8W97</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Adsorption of cis-1,4-polyisoprene at solid/liquid interface</title><source>Wiley-Blackwell Full Collection</source><creator>Vangani, Veena ; Rakshit, Animesh Kumar</creator><creatorcontrib>Vangani, Veena ; Rakshit, Animesh Kumar</creatorcontrib><description>The adsorption of cis‐1,4‐polyisoprene on alumina and silica gel was studied at three temperatures. The solvents used were toluene, chlorobenzene and various mixtures of both. The adsorption from the mixtures of the solvents was much less than from either of the pure solvents. The amount of adsorption was an inverse function of temperature. The thermodynamic quantities of adsorption at infinite dilution were obtained by extrapolation and at isosteric conditions. They were computed and discussed for all the systems.
Die Adsorption von Poly(cis‐1,4‐isopren) an Aluminiumoxid‐ und Siliziumdioxid‐Oberflächen wurde bei verschiedenen Temperaturen untersucht. Die Adsorptionsausbeute verhielt sich umgekehrt proportional zur Temperatur und war aus Toluol‐ und Chlorbenzol‐Lösungen größer als aus Mischungen von Toluol und Chlorbenzol. Die thermodynamischen Adsorptionsparameter bei unendlicher Verdünnung und isosteren Bedingungen wurden durch Extrapolation ermittelt und für alle untersuchten Systeme diskutiert.</description><identifier>ISSN: 0003-3146</identifier><identifier>EISSN: 1522-9505</identifier><identifier>DOI: 10.1002/apmc.1994.052200103</identifier><language>eng</language><publisher>Zug: Hüthig & Wepf Verlag</publisher><ispartof>Die Angewandte makromolekulare Chemie, 1994-03, Vol.220 (1), p.21-37</ispartof><rights>1994 Hüthig & Wepf Verlag, Zug</rights><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3403-4ee6392d7a7542226fcc8395f4d1fb6dfb4dcc2566e367416f9495b93bebdd23</citedby><cites>FETCH-LOGICAL-c3403-4ee6392d7a7542226fcc8395f4d1fb6dfb4dcc2566e367416f9495b93bebdd23</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapmc.1994.052200103$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapmc.1994.052200103$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids></links><search><creatorcontrib>Vangani, Veena</creatorcontrib><creatorcontrib>Rakshit, Animesh Kumar</creatorcontrib><title>Adsorption of cis-1,4-polyisoprene at solid/liquid interface</title><title>Die Angewandte makromolekulare Chemie</title><addtitle>Angew. Makromol. Chem</addtitle><description>The adsorption of cis‐1,4‐polyisoprene on alumina and silica gel was studied at three temperatures. The solvents used were toluene, chlorobenzene and various mixtures of both. The adsorption from the mixtures of the solvents was much less than from either of the pure solvents. The amount of adsorption was an inverse function of temperature. The thermodynamic quantities of adsorption at infinite dilution were obtained by extrapolation and at isosteric conditions. They were computed and discussed for all the systems.
Die Adsorption von Poly(cis‐1,4‐isopren) an Aluminiumoxid‐ und Siliziumdioxid‐Oberflächen wurde bei verschiedenen Temperaturen untersucht. Die Adsorptionsausbeute verhielt sich umgekehrt proportional zur Temperatur und war aus Toluol‐ und Chlorbenzol‐Lösungen größer als aus Mischungen von Toluol und Chlorbenzol. Die thermodynamischen Adsorptionsparameter bei unendlicher Verdünnung und isosteren Bedingungen wurden durch Extrapolation ermittelt und für alle untersuchten Systeme diskutiert.</description><issn>0003-3146</issn><issn>1522-9505</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1994</creationdate><recordtype>article</recordtype><recordid>eNqNj8tKAzEUQIMoWKtf4GY-wLR5TwMilMG2QqsuCi5DJg-ITpsxGbH9e6dUiktX997FOZcDwC1GI4wQGet2Y0ZYSjZCnBCEMKJnYID7HUqO-DkYIIQopJiJS3CV83t_SoHpANxPbY6p7ULcFtEXJmSI7xhsY7MPObbJbV2huyLHJthxEz6_gi3CtnPJa-OuwYXXTXY3v3MI1rPHdbWAy5f5UzVdQkNZ_5Y5J6gkttQlZ4QQ4Y2ZUMk9s9jXwvqaWWMIF8JRUTIsvGSS15LWrraW0CGgR61JMefkvGpT2Oi0VxipQ7869KtDvzr199TDkfoOjdv_B1HT11X1VwCPgpA7tzsJdPpQoqQlV2_Pc8VmYoKqxUqV9AcG8W97</recordid><startdate>199403</startdate><enddate>199403</enddate><creator>Vangani, Veena</creator><creator>Rakshit, Animesh Kumar</creator><general>Hüthig & Wepf Verlag</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>199403</creationdate><title>Adsorption of cis-1,4-polyisoprene at solid/liquid interface</title><author>Vangani, Veena ; Rakshit, Animesh Kumar</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3403-4ee6392d7a7542226fcc8395f4d1fb6dfb4dcc2566e367416f9495b93bebdd23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1994</creationdate><toplevel>online_resources</toplevel><creatorcontrib>Vangani, Veena</creatorcontrib><creatorcontrib>Rakshit, Animesh Kumar</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><jtitle>Die Angewandte makromolekulare Chemie</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Vangani, Veena</au><au>Rakshit, Animesh Kumar</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Adsorption of cis-1,4-polyisoprene at solid/liquid interface</atitle><jtitle>Die Angewandte makromolekulare Chemie</jtitle><addtitle>Angew. Makromol. Chem</addtitle><date>1994-03</date><risdate>1994</risdate><volume>220</volume><issue>1</issue><spage>21</spage><epage>37</epage><pages>21-37</pages><issn>0003-3146</issn><eissn>1522-9505</eissn><abstract>The adsorption of cis‐1,4‐polyisoprene on alumina and silica gel was studied at three temperatures. The solvents used were toluene, chlorobenzene and various mixtures of both. The adsorption from the mixtures of the solvents was much less than from either of the pure solvents. The amount of adsorption was an inverse function of temperature. The thermodynamic quantities of adsorption at infinite dilution were obtained by extrapolation and at isosteric conditions. They were computed and discussed for all the systems.
Die Adsorption von Poly(cis‐1,4‐isopren) an Aluminiumoxid‐ und Siliziumdioxid‐Oberflächen wurde bei verschiedenen Temperaturen untersucht. Die Adsorptionsausbeute verhielt sich umgekehrt proportional zur Temperatur und war aus Toluol‐ und Chlorbenzol‐Lösungen größer als aus Mischungen von Toluol und Chlorbenzol. Die thermodynamischen Adsorptionsparameter bei unendlicher Verdünnung und isosteren Bedingungen wurden durch Extrapolation ermittelt und für alle untersuchten Systeme diskutiert.</abstract><cop>Zug</cop><pub>Hüthig & Wepf Verlag</pub><doi>10.1002/apmc.1994.052200103</doi><tpages>17</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0003-3146 |
| ispartof | Die Angewandte makromolekulare Chemie, 1994-03, Vol.220 (1), p.21-37 |
| issn | 0003-3146 1522-9505 |
| language | eng |
| recordid | cdi_crossref_primary_10_1002_apmc_1994_052200103 |
| source | Wiley-Blackwell Full Collection |
| title | Adsorption of cis-1,4-polyisoprene at solid/liquid interface |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-07T19%3A38%3A17IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-wiley_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Adsorption%20of%20cis-1,4-polyisoprene%20at%20solid/liquid%20interface&rft.jtitle=Die%20Angewandte%20makromolekulare%20Chemie&rft.au=Vangani,%20Veena&rft.date=1994-03&rft.volume=220&rft.issue=1&rft.spage=21&rft.epage=37&rft.pages=21-37&rft.issn=0003-3146&rft.eissn=1522-9505&rft_id=info:doi/10.1002/apmc.1994.052200103&rft_dat=%3Cwiley_cross%3EAPMC052200103%3C/wiley_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |