Highly efficient formation of metal and metal alloy particles from methyl metal compounds by a single pulse laser irradiation

Highly efficient processes for fine particle formation of metal alloys and metal oxides were developed using a high‐power laser. In these processes, laser light was used only for the ignition of a thermal chain reaction. This reaction was suppressed by adding inert gases, and the suppression effect...

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Veröffentlicht in:Applied organometallic chemistry 1991-07, Vol.5 (4), p.303-307
Hauptverfasser: Shimo, Nobuo, Fujita, Masato, Kuma, Hitoshi
Format: Artikel
Sprache:eng
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Zusammenfassung:Highly efficient processes for fine particle formation of metal alloys and metal oxides were developed using a high‐power laser. In these processes, laser light was used only for the ignition of a thermal chain reaction. This reaction was suppressed by adding inert gases, and the suppression effect was in the order C3H8 > C2H6 > CH4 > He > Ar > Xe. Oxygen accelerated the reaction because of the large exothermicity of the reaction of oxygen with methyl metal compounds.
ISSN:0268-2605
1099-0739
DOI:10.1002/aoc.590050414