Novel synthesis of pinacols and sulfones promoted by SmNiCl2 bimetallic system

Novel synthesis of pinacols and sulfones promoted by SmNiCl2 bimetallic system

SmNiCl2 as a reductive system promoted reductive coupling of aryl adehydes and aryl ketone into pinacols in good yields and also promoted coupling reaction of aryl sulfonyl chlorides and active halides into sulfones in good yields. Copyright © 2011 John Wiley & Sons, Ltd. SmNiCl2 as a reductiv...

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Veröffentlicht in:Applied organometallic chemistry 2011-05, Vol.25 (5), p.331-334
Hauptverfasser: Ye, Yuyuan, Zhou, Qizhong, Zheng, Renhua, Jiang, Huajiang, Chen, Rener, Zhang, Yongmin
Format: Artikel
Sprache:eng
Schlagworte:
bimetallic system
pinacols
reductive coupling
Sm-NiCl2
sulfones
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Zusammenfassung:SmNiCl2 as a reductive system promoted reductive coupling of aryl adehydes and aryl ketone into pinacols in good yields and also promoted coupling reaction of aryl sulfonyl chlorides and active halides into sulfones in good yields. Copyright © 2011 John Wiley & Sons, Ltd. SmNiCl2 as a reductive system promoted reductive coupling of aryl adehydes and aryl ketone into pinacols in good yields and also promoted coupling reaction of aryl sulfonyl chlorides and active halides into sulfones in good yields.
ISSN:0268-2605
1099-0739
DOI:10.1002/aoc.1763