Inside Back Cover: Unraveling the Intertwining Factors Underlying the Assembly of High‐Nuclearity Heterometallic Clusters (Angew. Chem. Int. Ed. 37/2024)

Two structurally intricate heterometallic clusters with cores featuring multiple Platonic and Archimedean polyhedra were synthesized by ligand‐controlled co‐hydrolysis of Ni2+ and Dy3+ ions, as reported by Zhiping Zheng et al. in their Research Article (e202409109). Adjusting the amount of hydrolysi...

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Veröffentlicht in:Angewandte Chemie International Edition 2024-09, Vol.63 (37), p.n/a
Hauptverfasser: Xu, Na, Chen, Wanmin, Miao, Jun, Ding, Yousong, Zheng, Zhiping
Format: Artikel
Sprache:eng
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Zusammenfassung:Two structurally intricate heterometallic clusters with cores featuring multiple Platonic and Archimedean polyhedra were synthesized by ligand‐controlled co‐hydrolysis of Ni2+ and Dy3+ ions, as reported by Zhiping Zheng et al. in their Research Article (e202409109). Adjusting the amount of hydrolysis‐promoting base and the reaction temperature and duration afforded selectively the kinetic and thermodynamic species, respectively with a Dy112Ni76 and a Dy52Ni44 core.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.202414386