Mg(C 3 O 4 H 2 )(H 2 O) 2 : A New Ultraviolet Nonlinear Optical Material Derived from KBe 2 BO 3 F 2 with High Performance and Excellent Water-Resistance
Acquiring high-performance ultraviolet (UV) nonlinear optical (NLO) materials that simultaneously exhibit a strong second harmonic generation (SHG) coefficients, as short as possible SHG phase-matching (PM) wavelength and non-hygroscopic properties has consistently posed a significant challenge. Her...
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Veröffentlicht in: | Angewandte Chemie International Edition 2024-01, Vol.63 (2), p.e202315647 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Acquiring high-performance ultraviolet (UV) nonlinear optical (NLO) materials that simultaneously exhibit a strong second harmonic generation (SHG) coefficients, as short as possible SHG phase-matching (PM) wavelength and non-hygroscopic properties has consistently posed a significant challenge. Herein, through multicomponent modification of KBe
BO
F
(KBBF), an excellent UV NLO crystal, Mg(C
O
H
)(H
O)
, was successfully synthesized in malonic system. This material possesses a unique 2D NLO-favorable electroneutral [Mg(C
O
H
)
(H
O)
]
layer, resulting in the rare coexistence of a strong SHG response of 3×KDP (@1064 nm) and short PM wavelength of 200 nm. More importantly, it exhibits exceptional water resistance, which is rare among ionic organic NLO crystals. Theoretical calculations revealed that its excellent water-resistant may be originated from its small available cavity volumes, which is similar to the famous LiB
O
(LBO). Therefore, excellent NLO properties and stability against air and moisture indicate it should be a promising UV NLO crystal. |
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ISSN: | 1433-7851 1521-3773 |
DOI: | 10.1002/anie.202315647 |