Back Cover: Boron‐Centered Lewis Superacid through Redox‐Active Ligands: Application in C−F and S−F Bond Activation (Angew. Chem. Int. Ed. 13/2023)

Back Cover: Boron‐Centered Lewis Superacid through Redox‐Active Ligands: Application in C−F and S−F Bond Activation (Angew. Chem. Int. Ed. 13/2023)

One‐electron oxidation converts the ferrocene‐substituted borane into a Lewis superacid, as reported by Frank Breher, Jan Paradies, and co‐workers in their Communication (e202216959). The Lewis superacid activates almost inert carbon–fluorine and sulfur–fluorine bonds for reductions, alkylations, an...

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Veröffentlicht in:Angewandte Chemie International Edition 2023-03, Vol.62 (13), p.n/a
Hauptverfasser: Köring, Laura, Stepen, Arne, Birenheide, Bernhard, Barth, Simon, Leskov, Maxim, Schoch, Roland, Krämer, Felix, Breher, Frank, Paradies, Jan
Format: Artikel
Sprache:eng
Schlagworte:
C−F Bond Activation
Ferrocene
Fluorine
Lewis Superacids
S−F Bond Activation
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Zusammenfassung:One‐electron oxidation converts the ferrocene‐substituted borane into a Lewis superacid, as reported by Frank Breher, Jan Paradies, and co‐workers in their Communication (e202216959). The Lewis superacid activates almost inert carbon–fluorine and sulfur–fluorine bonds for reductions, alkylations, and arylations to form new chemical bonds.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.202301632