Inside Cover: Selective Implantation of Diamines for Cooperative Catalysis in Isoreticular Heterometallic Titanium–Organic Frameworks (Angew. Chem. Int. Ed. 21/2021)

A selective grafting route for heterometallic MOFs is described by Carlos Martí‐Gastaldo and co‐workers in their Research Article on page 11868. The different chemistry of Ti(IV) and Ca(II) sites is used to direct selective coordination of amines to the latter. This enables the combination of Lewis acid titanium centers and available ‐NH2 sites in two sizeable pores for cooperative cycloaddition of CO2 to epoxides at room temperature and atmospheric pressure.