Cover Picture: Luminescence and Light‐Driven Energy and Electron Transfer from an Exceptionally Long‐Lived Excited State of a Non‐Innocent Chromium(III) Complex (Angew. Chem. Int. Ed. 50/2019)
Inversion symmetry increases the excited‐state lifetime of a molecular ruby at room temperature in fluid solution to 4.5 ms while the photoluminescence quantum yield remains as high as 8.2 %, as shown by K. Heinze and co‐workers in their Research Article on page 18075. The chromium(III) complex [Cr(...
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Veröffentlicht in: | Angewandte Chemie International Edition 2019-12, Vol.58 (50), p.17879-17879 |
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Hauptverfasser: | , , , , , , , , , , , , , |
Format: | Artikel |
Sprache: | eng |
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Online-Zugang: | Volltext |
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Zusammenfassung: | Inversion symmetry increases the excited‐state lifetime of a molecular ruby at room temperature in fluid solution to 4.5 ms while the photoluminescence quantum yield remains as high as 8.2 %, as shown by K. Heinze and co‐workers in their Research Article on page 18075. The chromium(III) complex [Cr(tpe)2]3+ is furthermore competent in light‐induced electron and energy transfer processes, and thus resembles classical noble metal complexes. |
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ISSN: | 1433-7851 1521-3773 |
DOI: | 10.1002/anie.201914208 |