Cover Picture: Luminescence and Light‐Driven Energy and Electron Transfer from an Exceptionally Long‐Lived Excited State of a Non‐Innocent Chromium(III) Complex (Angew. Chem. Int. Ed. 50/2019)

Inversion symmetry increases the excited‐state lifetime of a molecular ruby at room temperature in fluid solution to 4.5 ms while the photoluminescence quantum yield remains as high as 8.2 %, as shown by K. Heinze and co‐workers in their Research Article on page 18075. The chromium(III) complex [Cr(...

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Veröffentlicht in:Angewandte Chemie International Edition 2019-12, Vol.58 (50), p.17879-17879
Hauptverfasser: Treiling, Steffen, Wang, Cui, Förster, Christoph, Reichenauer, Florian, Kalmbach, Jens, Boden, Pit, Harris, Joe P., Carrella, Luca M., Rentschler, Eva, Resch‐Genger, Ute, Reber, Christian, Seitz, Michael, Gerhards, Markus, Heinze, Katja
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Sprache:eng
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Zusammenfassung:Inversion symmetry increases the excited‐state lifetime of a molecular ruby at room temperature in fluid solution to 4.5 ms while the photoluminescence quantum yield remains as high as 8.2 %, as shown by K. Heinze and co‐workers in their Research Article on page 18075. The chromium(III) complex [Cr(tpe)2]3+ is furthermore competent in light‐induced electron and energy transfer processes, and thus resembles classical noble metal complexes.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201914208