Agostic NSi----H···Mo Complexes: From Curiosity to Catalysis

An uncommon catalyst: The β‐agostic NSiH⋅⋅⋅M complex 1 (Ar=2,6‐diisopropylphenyl) catalyzes a variety of hydrosilylation reactions. Stoichiometric reactions of 1 with unsaturated compounds proceed via the silanimine intermediate A and, in the case of olefins or nitriles, give products of SiC coupl...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Angewandte Chemie (International ed.) 2008-09, Vol.47 (40), p.7701-7704
Hauptverfasser: Khalimon, Andrey Y, Simionescu, Razvan, Kuzmina, Lyudmila G, Howard, Judith A.K, Nikonov, Georgii I
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:An uncommon catalyst: The β‐agostic NSiH⋅⋅⋅M complex 1 (Ar=2,6‐diisopropylphenyl) catalyzes a variety of hydrosilylation reactions. Stoichiometric reactions of 1 with unsaturated compounds proceed via the silanimine intermediate A and, in the case of olefins or nitriles, give products of SiC coupling, such as 2.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200802147