Agostic NSi----H···Mo Complexes: From Curiosity to Catalysis
An uncommon catalyst: The β‐agostic NSiH⋅⋅⋅M complex 1 (Ar=2,6‐diisopropylphenyl) catalyzes a variety of hydrosilylation reactions. Stoichiometric reactions of 1 with unsaturated compounds proceed via the silanimine intermediate A and, in the case of olefins or nitriles, give products of SiC coupl...
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Veröffentlicht in: | Angewandte Chemie (International ed.) 2008-09, Vol.47 (40), p.7701-7704 |
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Hauptverfasser: | , , , , |
Format: | Artikel |
Sprache: | eng |
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Online-Zugang: | Volltext |
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Zusammenfassung: | An uncommon catalyst: The β‐agostic NSiH⋅⋅⋅M complex 1 (Ar=2,6‐diisopropylphenyl) catalyzes a variety of hydrosilylation reactions. Stoichiometric reactions of 1 with unsaturated compounds proceed via the silanimine intermediate A and, in the case of olefins or nitriles, give products of SiC coupling, such as 2. |
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ISSN: | 1433-7851 1521-3773 |
DOI: | 10.1002/anie.200802147 |