Shape-Selective Hydrogenation and Oxidation over a Platinum-Containing Ultramicroporous Heteropolyoxometallic Compound

Shape-Selective Hydrogenation and Oxidation over a Platinum-Containing Ultramicroporous Heteropolyoxometallic Compound

Preferentially smaller molecules are oxidized and hydrogenated in the presence of the ultramicroporous (pore diameter < 5.9 Å), platinum‐containing (0.5 wt%) heteropolyoxometalate compound Pt/Cs2.1H0.9PW12O40, according to studies with methane/2,2‐dimethylpropane and ethene/cyclohexene (shown sch...

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Veröffentlicht in:Angewandte Chemie International Edition 1997-01, Vol.36 (24), p.2833-2835
Hauptverfasser: Yoshinaga, Yusuke, Seki, Kohei, Nakato, Teruyuki, Okuhara, Toshio
Format: Artikel
Sprache:eng
Schlagworte:
heterogeneous catalysis
heteropolyacids
hydrogenations
oxidations
platinum
shape-selectivity
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Beschreibung
Zusammenfassung:Preferentially smaller molecules are oxidized and hydrogenated in the presence of the ultramicroporous (pore diameter < 5.9 Å), platinum‐containing (0.5 wt%) heteropolyoxometalate compound Pt/Cs2.1H0.9PW12O40, according to studies with methane/2,2‐dimethylpropane and ethene/cyclohexene (shown schematically on the right).
ISSN:0570-0833
1521-3773
DOI:10.1002/anie.199728331